We tend not to have a whole lot of structure to our day, but Katie just turned 2. When she gets up, she plays upstairs for a bit - she has a whole lot of Little People up there which she loves -- we go downstairs, she has breakfast and plays with her toys downstairs. We watch Sesame Street together at 9 AM -- she usually plays during that, sometimes we'll read some books together. I try to hang out with her during that time -- also at some point during SS, her sister (4 months) needs to nap, so at that point I bring the baby upstairs to put her down -- Katie either stays downstairs or follows me up. She makes a lot of noise, but the baby seems to be used to it by now. Once Allie is asleep, I lock Katie in our room with me and take a shower (bathroom connects to the bedroom) -- she's got toys in there and I usually leave the tv on. I let her decide what to do then -- I'll often suggest some sort of art/craft activity (trust me, nothing fancy, just coloring in a coloring book usually).
Allie wakes at some point before lunch and I feed her and we have lunch -- read some books, play with toys and then it's time for Katie's nap and Allie's second nap -- if all goes well, they nap at the same time. When Katie wakes, we usually go outside or run errands as long as Allie is awake as well. That way I feel like when I'm making dinner she hasn't been in for awhile and will (hopefully) let me make some dinner in relative peace. She'll watch TV at this time too. After dinner, she plays with her dad while I put Allie to bed.
Katie loves her Little People, also her trains, Legos, books, dolls....generally keeps her busy. I try to throw some more structured activities in along with her just playing with her toys and having fun.
HTH!